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AbstractAbstract
[en] The column calibration factors Fs as a quadratic function of the mean temperatures T-bar are worked out from the estimated values of the logarithmic maximum separation factors ln qmax of inert gas isotopic mixtures and their available TD factors αTs' in three columns of comparatively larger geometrical lengths and of varying sizes. The ln qmax are determined from the pressure dependence of ln qe in those columns measured by W.M. Rutherford et al. and W.J. Roos et al. The nature of temperature variation of Fs, which depends entirely on the column geometry, allows us to estimate the temperature dependence of αTs' for a wide temperature range. Our αTs' through the use of Fs are shown to have almost the same order of magnitudes and the same trends as the theoretical ones, while there are larger discrepancies when αTs' are estimated by other methods. This signifies the usefulness of Fs in column measurements. (author)
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