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AbstractAbstract
[en] The T-P diagrams of Ti-H and Ti-D systems were studied at pressures of 25 to 65 kbar, and a marked isotope effect was observed for the minimum pressure when the high-pressure phase appeared. The occurrence of another high-pressure phase is concluded from splitting of one of the transformation lines at P>40 (50) kbar. Transformations of the χ-phase quenched under pressure (χ → κ+Ti → γ+Ti in TiH(D)∼0.75) were studied at P=1 atm by calorimetric and neutron scattering techniques. A double-peaked exothermal effect evidenced metastability both of χ-and intermediate κ-phases. The hydrogen in the intermediate κ-phase was partially ordered in tetrahedral interstices on alternate {110} planes. Complete H ordering resulted in stoichiometric γ-TiH and precipitation of disperse Ti. Parameters of the transformations exhibited a considerable isotope effect. The γ to α+δ transformation in the Zr-H system is reversible, therefore, γ-ZrH is a stable phase below the transformation temperature. A phase transformation was found in deficient dihydrides, ZrH1.59 and ZrD1.69, under pressure. (orig.)
Primary Subject
Source
3. international symposium on metal-hydrogen systems: Fundamentals and applications; Uppsala (Sweden); 8-12 Jun 1992
Record Type
Journal Article
Literature Type
Conference
Journal
Zeitschrift fuer Physikalische Chemie. Neue Folge; ISSN 0044-3336;
; CODEN ZPYFA7; v. 179(pt.1-2); p. 289-299

Country of publication
COHERENT SCATTERING, CRYSTAL DEFECTS, DEUTERIUM COMPOUNDS, DIAGRAMS, DIFFRACTION, HEAT TREATMENTS, HYDRIDES, HYDROGEN COMPOUNDS, INFORMATION, PHYSICAL PROPERTIES, POINT DEFECTS, SCATTERING, SEPARATION PROCESSES, THERMODYNAMIC PROPERTIES, TITANIUM COMPOUNDS, TRANSITION ELEMENT COMPOUNDS, ZIRCONIUM COMPOUNDS
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