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AbstractAbstract
[en] Uranium (VI) was determined by square wave adsorptive stripping voltammetry on a rotating-disc mercury-film electrode using 8-hydroxyquinoline as a complexing agent (batch mode), or, alternatively, on a wall jet mercury-film electrode with cupferron as complexing agent (flow-through mode). For the flow-through configuration, the combination of a novel wall jet cell with an automated flow system and a commercial computer-controlled potentiostat allowed complete keyboard control of the sequence of operations. Both continuous flow and flow injection (FI) schemes for preconcentration were assessed, and various instrumental parameters are discussed. The batch and flow methods were, finally, applied to the determination of UVI in a reference sea-water sample with accuracies of 7.2 and 4.2%, respectively, and relative standard deviations of 7.8 and 8.3%, respectively. (Author)
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Source
International symposium on electroanalysis in biomedical, environmental and industrial sciences; Loughborough (United Kingdom); 20-23 Apr 1993
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Journal Article
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Conference
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