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AbstractAbstract
[en] Five superconductors of the Nd1+xBa2-xCu3O6.5±y type (x 0.00, 0.05, 0.10, 0.15, and 0.20) are prepared. The orthorhombic crystal lattice observed at x = 0 gradually transforms into a tetragonal structure at increasing values of x. Resistivity measurements (dc) show a metal-semiconductor type transition at temperatures above Tc. Tc ranges from 92 to 72 K by increasing values of x from 0.00 to 0.20, respectively. The oxygen content (y) increases with increasing x. Comparison of calculated and experimental values of y suggests that Nd is present in the form of Nd2O3. In contrast to earlier reports, it appears that the behavior observed are due to a mixture of Nd2O3 and NdBa2Cu3O6.5±y instead of Nd1+xBa2-xCu3O6.5±y suggested earlier. (orig.)
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ALKALINE EARTH METAL COMPOUNDS, BARIUM COMPOUNDS, CHALCOGENIDES, COPPER COMPOUNDS, CRYSTAL LATTICES, CRYSTAL STRUCTURE, ELECTRICAL PROPERTIES, ELEMENTS, NEODYMIUM COMPOUNDS, NONMETALS, OXIDES, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, RARE EARTH COMPOUNDS, SUPERCONDUCTORS, TEMPERATURE RANGE, TRANSITION ELEMENT COMPOUNDS
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