Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.028 seconds
Haas, P.A.; Rudolph, J.C.; Bell, J.T.
Oak Ridge National Lab., TN (United States). Funding organisation: USDOE, Washington, DC (United States)1994
Oak Ridge National Lab., TN (United States). Funding organisation: USDOE, Washington, DC (United States)1994
AbstractAbstract
[en] Molten salt oxidation (MSO) is a process in which organic wastes are oxidized by sparging them with air through a bed of molten sodium carbonate (bp 851 degrees C) at ≥ 900 degrees C. This process is readily applicable to the mixed waste because acidic products from Cl, S, P, etc., in the waste, along with most metals and most radionuclides, are retained within the melt as oxides or salts. Rockwell International has studied the application of MSO to various wastes, including some mixed waste. A unit used by Rockwell to study the mixed waste treatment is presently in use at Oak Ridge National Laboratory (ORNL). ORNL's studies to date have concentrated on chemical flowsheet questions. Concerns that were studied included carbon monoxide (CO) emissions, NOx, emissions, and metal retention under a variety of conditions. Initial experiments show that CO emissions increase with increasing NaCl content in the melt, increasing temperature, and increasing airflow. Carbon monoxide content is especially high (> 2000 ppm) with high chlorine content (> 10%). Thermal NOx, emissions are relatively low ( < 5 ppm) at temperatures < 1000 degrees C. However, most (85--100%) of the nitrogen in the feed as organic nitrate or amine was released as NOx, The metal contents of the melt and of knockout pot samples of condensed salt show high volatilities of Cs as CsCl. Average condensed salt concentrations were 60% for barium and 100% for strontium and cobalt. The cerium disappeared -- perhaps from deposition on the alumina reactor walls
Primary Subject
Secondary Subject
Source
Jun 1994; 27 p; CONTRACT AC05-84OR21400; Also available from OSTI as DE94017531; NTIS; US Govt. Printing Office Dep
Record Type
Report
Report Number
Country of publication
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue