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Ruskeeniemi, T.; Blomqvist, R.; Ahonen, L.
The Palmottu Analogue Project, Progress Report 1993. The behaviour of natural radionuclides in and around uranium deposits, Nr. 71994
The Palmottu Analogue Project, Progress Report 1993. The behaviour of natural radionuclides in and around uranium deposits, Nr. 71994
AbstractAbstract
[en] Uraninite is the major uraniferous mineral in the Precambrian U-Th rich pegmatites at Palmottu. Most euhedral uraninite grains were partially altered by silica-rich hydrothermal solutions during the late stage pegmatitic crystallization. The dominant secondary mineral is uranium silicate, with a chemical composition similar to that of coffinite (USiO4 * Nh2O). The simultaneous formation of galena and other sulfides with the uranium silicate indicates that the alteration took place under reducing conditions. Hence, uranium occurs predominantly in the uranous (U4+) state. Preliminary mass balance calculations imply that significant amounts of U, Th, and Pb were released during the replacement process. As the Palmottu U-Th deposit extends from ground level to distinctly reduced parts of the bedrock, it affords the opportinity of studying the stability and alteration of uraninite as an analogue for spent nuclear fuel under various redox conditions. (orig.) (28 refs., 5 figs., 1 tab.)
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Ruskeeniemi, T.; Blomqvist, R. (Geological Survey of Finland, Espoo (Finland)); Suksi, J. (Helsinki Univ. (Finland). Dept. of Radiochemistry); Niini, H. (Helsinki Univ. of Technology, Espoo (Finland). Lab. of Engineering Geology and Geophysics) (eds.); Geological Survey of Finland, Espoo (Finland); 97 p; ISBN 951-690-542-0;
; 1994; p. 53-64

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