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AbstractAbstract
[en] Monoclinic τ2-Al13Co4, τ3-Al13Co4 and τ4-Al13Co4 phases with a and c parameters about τ2, τ3 and τ4 times [τ = (1 + 51/2)/2 = 1.61803, which is the golden number], respectively, greater than their counterparts in Al13Co4 (space group Cm, a = 1.5183, b = 0.8122, c = 1.2340 nm, β = 107 54' [Hudd and Taylor (1962). Acta Cryst. 15, 441-442]) have been found by selected-area electron diffraction and high-resolution electron microscopy (HREM). The [010] HREM images showed that these τ-inflated phases have a similar pentagonal layer structure as Al13Co4, but the edge length of the pentagons is τ2, τ3 and τ4 times larger, respectively, than that in Al13Co4. This explains why these τ-inflated phases have about the same β angle (≅108 ) and b representing a repeat unit of the stacking of these pentagonal layers. The τ2 pentagon (1.23 nm) consists of six smaller pentagons (0.47 nm) existing in Al13Co4, one inverted and five of the same orientation as the τ2 pentagon. Similarly, the τ3 pentagon (2.00 nm) consists of six τ pentagons (0.76 nm), and the τ4 pentagon (3.23 nm) of six τ2 pentagons which in turn contain six 0.47 nm pentagons in each of them. The greater the inflation, the larger the unit-cell parameters, and the better the approximation of its structure to that of a decagonal quasicrystal (DOC). In other words, a DQC is considered to be the end member of this family of τ-inflated phases. (orig.)
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Acta Crystallographica. Section B: Structural Science; ISSN 0108-7681;
; CODEN ASBSDK; v. 51(1); p. 36-43

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