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AbstractAbstract
[en] Structural and magnetic properties of the GdFe12-xMox compounds having the ThMn12 type of structure were studied. Rare-earth nitrides of the composition GdFe12-xMoxNy were prepared by the reaction of GdFe12-xMox with nitrogen gas at 475 C. The crystal structure and lattice constants have been determined for all compounds. The lattice expansion of the nitrogenated compounds is mainly along the a-axis, the Curie temperatures are increased by about 110 K. We investigated the effect of interstitial nitrogen on the magnetic properties and the 155Gd Moessbauer spectrum of GdFe12-xMox. Values of the electric field gradient Vzz derived from the quadrupole splitting of the spectra were strongly negative, with Vzz=-21.3x1021 V m-2 and Vzz=-19.9x1021 V m-2 for x=1.5 and 3.0, respectively. Nitrogenation is shown to lead to a sign reversal of the 4f as well as of the 3d sublattice anisotropies. ((orig.))
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Journal Article
Journal
Journal of Magnetism and Magnetic Materials; ISSN 0304-8853;
; CODEN JMMMDC; v. 146(1-2); p. 123-128

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ANISOTROPY, CRYSTAL STRUCTURE, CURIE POINT, ELECTRIC FIELDS, GADOLINIUM 155, GADOLINIUM ALLOYS, INTERSTITIALS, IRON ALLOYS, ISOMER SHIFT, LATTICE PARAMETERS, MAGNETIC FIELDS, MAGNETIC PROPERTIES, MOESSBAUER EFFECT, MOLYBDENUM ALLOYS, NITROGEN, NITROGEN ADDITIONS, PERMANENT MAGNETS, TEMPERATURE DEPENDENCE
ALLOYS, CRYSTAL DEFECTS, ELEMENTS, EQUIPMENT, EVEN-ODD NUCLEI, GADOLINIUM ISOTOPES, INTERMEDIATE MASS NUCLEI, ISOTOPES, MAGNETS, NONMETALS, NUCLEI, PHYSICAL PROPERTIES, POINT DEFECTS, RARE EARTH ALLOYS, RARE EARTH NUCLEI, STABLE ISOTOPES, THERMODYNAMIC PROPERTIES, TRANSITION ELEMENT ALLOYS, TRANSITION TEMPERATURE
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