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Solbrig, C.W.; Krsul, J.R.; Olsen, D.N.
Argonne National Lab., Idaho Falls, ID (United States). Funding organisation: USDOE, Washington, DC (United States)1994
Argonne National Lab., Idaho Falls, ID (United States). Funding organisation: USDOE, Washington, DC (United States)1994
AbstractAbstract
[en] A corrosion cycle for uranium is postulated which can be used to assess whether a given storage situation might produce fire hazards and/or continual uranium corrosion. A significant reaction rate of uranium and moisture occurs at room temperature which produces uranium oxide and hydrogen. If the hydrogen cannot escape, it will react slowly with uranium to form uranium hydride. The hydride is pyrophoric at room temperature when exposed to air. Either the hydrogen or the hydride can produce a dangerous situation as demonstrated by two different incidents described here. Long-term corrosion will occur even if the normal precautions are taken as is demonstrated by the long-term storage of stainless steel clad uranium fuel plates. The major initiator of these problems is attributed to any moisture condensed on the metal or any brought in by the cover gas. The postulated corrosion cycle is used to suggest ways to circumvent these problems
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1994; 6 p; Spent nuclear fuel meeting: challenges and initiatives; Salt Lake City, UT (United States); 14-16 Dec 1994; CONF-941207--34; CONTRACT W-31109-ENG-38; Also available from OSTI as DE95009902; NTIS; US Govt. Printing Office Dep
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Report
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Conference
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ACTINIDE COMPOUNDS, ACTINIDES, CHALCOGENIDES, CHEMICAL REACTIONS, DECOMPOSITION, ELEMENTS, EPITHERMAL REACTORS, EXPERIMENTAL REACTORS, FAST REACTORS, HAZARDS, HYDRIDES, HYDROGEN COMPOUNDS, METALS, OXIDES, OXYGEN COMPOUNDS, REACTORS, RESEARCH AND TEST REACTORS, RESEARCH REACTORS, SOLVOLYSIS, STORAGE, URANIUM COMPOUNDS, ZERO POWER REACTORS
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