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Richmann, M.K.; Reed, D.T.
Argonne National Lab., IL (United States). Funding organisation: USDOE, Washington, DC (United States)1995
Argonne National Lab., IL (United States). Funding organisation: USDOE, Washington, DC (United States)1995
AbstractAbstract
[en] Information on the spectroscopy of plutonium-organic complexes is needed to help establish the speciation of these complexes under environmentally relevant conditions. Laser photoacoustic spectroscopy (LPAS) and absorption spectrometry were used to characterize the Pu(IV)-citrate and Pu(IV)-nitrilotriacetic acid (NTA) complexes at concentrations of 10-3--10-7 M in aqueous solution. Good agreement was observed between the band shape of the LPAS and absorption spectra for the Pu(IV)-NTA complex. Agreement for the Pu(IV)-citrate complex was not quite as good. In both cases, a linear dependence of the LPAS signal on laser power and total concentration of the complexes was noted. This work is part of an ongoing research effort to study key subsurface interactions of plutonium-organic complexes
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1995; 8 p; Fall meeting of the Materials Research Society (MRS); Boston, MA (United States); 27 Nov - 1 Dec 1995; CONF-951155--30; CONTRACT W-31109-ENG-38; Also available from OSTI as DE96004773; NTIS; US Govt. Printing Office Dep
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Report
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Conference; Numerical Data
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