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Totemeier, T.C.; Hayes, S.L.; Pahl, R.G.; Crawford, D.C.
Argonne National Lab., Idaho Falls, ID (United States). Funding organisation: USDOE Assistant Secretary for Nuclear Energy, Washington, DC (United States)1997
Argonne National Lab., Idaho Falls, ID (United States). Funding organisation: USDOE Assistant Secretary for Nuclear Energy, Washington, DC (United States)1997
AbstractAbstract
[en] This paper presents the results of recent experimentation and analysis of the pyrophoric behavior of corroded Zero Power Physics Reactor (ZPPR) HEU fuel plates and the implications of these results for the handling, drying, and passivation of uranium metal fuels stored in water basins. The ZPPR plates were originally clad in 1980; crevice corrosion of the uranium metal in a dry storage environment has occurred due to the use of porous cladding end plugs. The extensive corrosion has resulted in bulging and, in some cases, breaching of the cladding over a 15 year storage period. Processing of the plates has been initiated to recover the highly enriched uranium metal and remove the storage vulnerability identified with the corroded plates, which have been shown to contain significant quantities of the pyrophoric compound uranium hydride (UH3). Experiments were undertaken to determine effective passivation techniques for the corrosion product; analysis and modeling was performed to determine whether heat generated by rapid hydride re-oxidation could ignite the underlying metal plates. The results of the initial passivation experiment showed that simple exposure of the hydride-containing corrosion product to an Ar-3 vol.% O2 environment was insufficient to fully passivate the hydride--flare-up of the product occurred during subsequent vigorous handling in air. A second experiment demonstrated that corrosion product was fully stable following grinding of the product to a fine powder in the Ar-3 vol.% O2 atmosphere. Numerical modeling of a corroded plate indicated that ignition of the plate due to the heat from hydride re-oxidation was likely if hydride fractions in the corrosion product exceeded 30%
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1997; 5 p; National spring meeting and petrochemical exposition of the American Institute of Chemical Engineers (AIChE); Houston, TX (United States); 10-13 Mar 1997; 2. plant operations and design conference; Houston, TX (United States); 10-13 Mar 1997; CONF-970321--6; CONTRACT W-31109-ENG-38; Also available from OSTI as DE97004674; NTIS; US Govt. Printing Office Dep
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Report
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Conference
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ACTINIDE COMPOUNDS, ACTINIDES, CHEMICAL REACTIONS, ELEMENTS, ENTHALPY, EPITHERMAL REACTORS, EXPERIMENTAL REACTORS, FAST REACTORS, HYDRIDES, HYDROGEN COMPOUNDS, METALS, PHYSICAL PROPERTIES, REACTORS, RESEARCH AND TEST REACTORS, RESEARCH REACTORS, STORAGE, THERMODYNAMIC PROPERTIES, URANIUM COMPOUNDS, ZERO POWER REACTORS
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