[en] Gamma-ray spectra acquired with high-energy resolution by the spectral gamma logging systems (SGLSs) at the U.S. Department of Energy Hanford Tank Farms, Richland, Washington, are being analyzed for spectral shape characteristics. These spectral shapes, together with a conventional peak-area analysis, enable an analyst not only to identify the gamma-emitting species but also to determine in many instances its spatial distribution around a borehole and to identify the presence of the bremsstrahlung-producing contaminant ⁹⁰Sr. The analysis relies primarily on the results of computer simulations of gamma spectra from the predominant radionuclide ¹³⁷Cs for various spatial distributions. This log analysis methodology has evolved through an examination of spectral features from spectral logs taken at the SX, BY, and U Tank Farms at the Hanford Site. Initial results determined with this technique show it is possible, in most cases, to distinguish between concentrations of ¹³⁷Cs. Work is continuing by experimentally measuring shape factors, incorporating spectrum shape processing in routine log analysis, and extending the techniques to additional radionuclides