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Whorlow, K.M.; Hutto, F.B. Jr.
Nuclear Regulatory Commission, Washington, DC (United States). Div. of Engineering Technology; Tutco Scientific Corp., Grand Junction, CO (United States). Funding organisation: Nuclear Regulatory Commission, Washington, DC (United States)1997
Nuclear Regulatory Commission, Washington, DC (United States). Div. of Engineering Technology; Tutco Scientific Corp., Grand Junction, CO (United States). Funding organisation: Nuclear Regulatory Commission, Washington, DC (United States)1997
AbstractAbstract
[en] The drip procedure from the Standard Test Method for Evaluating the Influence of Thermal Insulation on External Stress Corrosion Cracking Tendency of Austenitic Stainless Steel (ASTM C 692-95a) was used to research the effect of halogens and inhibitors on the External Stress Corrosion Cracking (ESCC) of Type 304 stainless steel as it applies to Nuclear Regulatory Commission Regulatory Guide 1.36, Nonmetallic Thermal Insulation for Austenitic Stainless Steel. The solutions used in this research were prepared using pure chemical reagents to simulate the halogens and inhibitors found in insulation extraction solutions. The results indicated that sodium silicate compounds that were higher in sodium were more effective for preventing chloride-induced ESCC in Type 304 austenitic stainless steel. Potassium silicate (all-silicate inhibitor) was not as effective as sodium silicate. Limited testing with sodium hydroxide (all-sodium inhibitor) indicated that it may be effective as an inhibitor. Fluoride, bromide, and iodide caused minimal ESCC which could be effectively inhibited by sodium silicate. The addition of fluoride to the chloride/sodium silicate systems at the threshold of ESCC appeared to have no synergistic effect on ESCC. The mass ratio of sodium + silicate (mg/kg) to chloride (mg/kg) at the lower end of the NRC RG 1.36 Acceptability Curve was not sufficient to prevent ESCC using the methods of this research
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Jul 1997; 48 p; Also available from OSTI as TI97007395; NTIS; GPO
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ALLOYS, AUSTENITIC STEELS, BROMINE COMPOUNDS, CARBON ADDITIONS, CHEMICAL REACTIONS, CHLORINE COMPOUNDS, CHROMIUM ALLOYS, CHROMIUM-NICKEL STEELS, CORROSION, CORROSION RESISTANT ALLOYS, DATA, FLUORINE COMPOUNDS, HALIDES, HALOGEN COMPOUNDS, HEAT RESISTANT MATERIALS, HEAT RESISTING ALLOYS, HIGH ALLOY STEELS, INFORMATION, IODINE COMPOUNDS, IRON ALLOYS, IRON BASE ALLOYS, MATERIALS, NICKEL ALLOYS, NUMERICAL DATA, STAINLESS STEELS, STEEL-CR19NI10, STEELS, TESTING, TRANSITION ELEMENT ALLOYS
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