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Temperature-induced phase transitions during ion-beam irradiation of the perovskite-structure oxides
Meldrum, A.; Boatner, L.A.; Ewing, R.C.
Oak Ridge National Lab., TN (United States); New Mexico Univ., Albuquerque, NM (United States). Funding organisation: USDOE Office of Energy Research, Washington, DC (United States)1997
Oak Ridge National Lab., TN (United States); New Mexico Univ., Albuquerque, NM (United States). Funding organisation: USDOE Office of Energy Research, Washington, DC (United States)1997
AbstractAbstract
[en] Several perovskite-structure oxide compounds, including CaTiO3, SrTiO3, BaTiO3, KNbO3, and KTaO3 were irradiated by 800 keV Kr+ ions in order to investigate and compare their response to heavy-ion irradiation. The critical amorphization temperature Tc, above which amorphization temperature Tc, above which amorphization could not be induced, was found to increase in the order SrTiO3 → CaTiO3 → BaTiO3 → KNbO3 → KTaO3. No single physical parameter explains the observed sequence, although Tc correlates well with the melting temperatures. The well-known temperature-driven phase transformations in these materials did not have a significant effect on the dose required for amorphization. Domain boundaries were observed in the pristine samples; however, after only a low dose, the boundaries became poorly defined and, with increasing dose, eventually disappeared. Dislocation loops were observed to aggregate at the domain boundaries
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1997; 6 p; 1997 fall meeting of the Materials Research Society; Boston, MA (United States); 1-5 Dec 1997; CONF-971201--; CONTRACT AC05-96OR22464; FG03-93ER45498; ALSO AVAILABLE FROM OSTI AS DE98001935; NTIS; INIS; US GOVT. PRINTING OFFICE DEP
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