Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.017 seconds
Ren Xian Wen; Zhang Yuan
New methods and techniques for decontamination in maintenance or decommissioning operations. Results of a co-ordinated research programme 1994-19981998
New methods and techniques for decontamination in maintenance or decommissioning operations. Results of a co-ordinated research programme 1994-19981998
AbstractAbstract
[en] The corrosion rate of stainless steel in nitric acid solution will be enhanced by existence of Ce4+. The goal of this study is to develop a circular decontamination process in medium of nitric acid, in order to use it in a loop clean up. That needs a specially designed electrolytic cell to oxidize the Ce3+ into Ce4+. This regenerator's structure should be simple and easy to operate, and can meet the requirements of practical decontamination operation. The concentration of Ce4+ in the nitric acid solution was selected to provide a suitable corrosion rate to contaminated stainless steel. The total concentration of cerium (III+IV) was also optimized to ensure that the regeneration rate of Ce4+ could satisfy the consumption rate of Ce4+ during decontaminating process. The operation parameters were selected strictly on the basis of our experimental results, so that the regeneration rate of Ce4+ can be higher reasonably in proper operation conditions and not arise any problem related to safety of operation and nuclear aspects. It is considered that this decontamination process could be applied into either decommissioning or maintenance stage of nuclear facilities. The concentration of Ce4+ and temperature are the main factors for corrosion rate, other factors should also be considered during decision of decontamination process. With the regenerator developed under contract No 7959/RB could obtain sufficient decontamination factors, when use following conditions: concentration of Ce4+ is higher than 0.2 mol/1, the total concentration of cerium (III+IV) is higher than 0.4 mol/1, concentration of nitric acid is higher than 2 mol/1, temperature of decontamination operation is within 25 deg. C - 40 deg. C and temperature of regeneration is within 40 deg C - 50 deg.C
Primary Subject
Secondary Subject
Source
International Atomic Energy Agency, Vienna (Austria); 187 p; ISSN 1011-4289;
; Jun 1998; p. 51-63; 8 refs, 9 figs, 17 tabs

Record Type
Report
Report Number
Country of publication
Reference NumberReference Number
Related RecordRelated Record
INIS VolumeINIS Volume
INIS IssueINIS Issue