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AbstractAbstract
[en] We have studied with neutron scattering techniques betaine calcium chloride dihydrate (BCCD), a dielectric aperiodic crystal which displays a Devil's staircase type phase diagram made up of several incommensurate and commensurate phases, having a range of stability very sensitive to temperature, electric field and hydrostatic pressure. We have measured a global hysteresis of δ(T) of about 2-3 K in the two incommensurate phases. A structural study of the modulated commensurate phases 1/4 and 1/5 allows us to evidence that the atomic modulation functions are anharmonic. The relevance of the modelization of the modulated structure by polar Ising pseudo-spins is then directly established. On the basis of group theory calculation in the four dimensional super-space, we interpret this anharmonic modulation as a soliton regime with respect to the lowest-temperature non modulated ferroelectric phase. The continuous character of the transition to the lowest-temperature non modulated phase and the diffuse scattering observed in this phase are accounted for the presence of ferroelectric domains separated by discommensurations. Furthermore, we have shown that X-rays induce in BCCD a strong variation with time of irradiation of the intensity of satellite peaks, and more specifically for third order ones. This is why the 'X-rays' structural model is found more harmonic than the 'neutron' one. Under electric field applied along the vector b axis, we confirm that commensurate phases with δ = even/odd are favoured and hence are polar along this direction. We have evidenced at 10 kV / cm two new higher order commensurate phases in the phase INC2, corroborating the idea of a 'complete' Devil's air-case phase diagram. A phenomenon of generalized coexistence of phases occurs above 5 kV / cm. We have characterized at high field phase transitions between 'coexisting' phases, which are distinguishable from classical lock-in transitions. Under hydrostatic pressure, our results contradict the pressure - temperature phase diagrams previously determined or extrapolated above room-temperature. (author)
Original Title
Etude par diffusion de neutrons du chlorure de calcium et de betaine dihydrate sous champ externe applique (temperature, champ electrique et pression hydrostatique)
Source
17 Nov 1997; 202 p; 122 refs.; These (D. es Sc.)
Record Type
Report
Literature Type
Thesis/Dissertation
Report Number
Country of publication
ALKALINE EARTH METAL COMPOUNDS, CALCIUM COMPOUNDS, CALCIUM HALIDES, CHLORIDES, CHLORINE COMPOUNDS, COHERENT SCATTERING, DIELECTRIC PROPERTIES, DIFFRACTION, ELECTRICAL PROPERTIES, ELECTROMAGNETIC RADIATION, HALIDES, HALOGEN COMPOUNDS, IONIZING RADIATIONS, PHASE TRANSFORMATIONS, PHYSICAL PROPERTIES, RADIATIONS, SCATTERING
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