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Murray, A.M.; Karraker, D.G.
Westinghouse Savannah River Company, Aiken, SC (United States); Westinghouse Savannah River Co., Aiken, SC (United States). Funding organisation: USDOE Office of Environmental Restoration and Waste Management, Washington, DC (United States)1998
Westinghouse Savannah River Company, Aiken, SC (United States); Westinghouse Savannah River Co., Aiken, SC (United States). Funding organisation: USDOE Office of Environmental Restoration and Waste Management, Washington, DC (United States)1998
AbstractAbstract
[en] The solutions from the dissolution of sand, slag, and crucible (SS ampersand C) material are sufficiently different from previous solutions processed via the F-Canyon Purex process that the effectiveness of individual process steps needed to be ascertained. In this study, the effectiveness of gelatin strike was tested under a variety of conditions. Specifically, several concentrations of silica, fluoride, nitric acid (HNO3), boric acid (H3BO3), and aluminium nitrate nonahydrate (ANN) were studied. The disengagement times of surrogate and plant SS ampersand C dissolver solutions from plant solvent also were measured. The results of the tests indicate that gelatin strike does not coagulate the silica at the low concentration of silica (30 ppm) expected in the SS ampersand C dissolver solutions because the silicon is complexed with fluoride ions (e.g., SiF6-2). The silicon fluoride complex is expected to remain with the aqueous phase during solvent extraction. The disengagement times of the dissolver solutions from the plant solvent were not affected by the presence of low concentrations of silica and no third phase formation was observed in the disengagement phase with the low silica concentrations. Tests of surrogate SS ampersand C dissolver solutions with higher concentration of silica (less than 150 ppm) did show that gelatin strike followed by centrifugation resulted in good phase disengagement of the surrogate SS ampersand C dissolver solution from the plant dissolver solution. At the higher silica concentrations, there is not sufficient fluoride to complex with the silica, and the silica must be entrained by the gelatin and removed from the dissolver solution prior to solvent extraction
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Source
May 1998; 18 p; CONTRACT AC09-96SR18500; ALSO AVAILABLE FROM OSTI AS DE98054751; NTIS; US GOVT. PRINTING OFFICE DEP
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Report
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ALUMINIUM COMPOUNDS, BORON COMPOUNDS, CHALCOGENIDES, COLLOIDS, DISPERSIONS, EQUIPMENT, EXTRACTION, FLUORIDES, FLUORINE COMPOUNDS, HALIDES, HALOGEN COMPOUNDS, HYDROGEN COMPOUNDS, INORGANIC ACIDS, INORGANIC COMPOUNDS, NITRATES, NITROGEN COMPOUNDS, ORGANIC COMPOUNDS, OXIDES, OXYGEN COMPOUNDS, PROTEINS, REPROCESSING, SEPARATION PROCESSES, SILICON COMPOUNDS, SILICON HALIDES, SILICON OXIDES
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