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Hill, M.A.; Butt, D.P.; Lillard, R.S.
Los Alamos National Lab., NM (United States). Funding organisation: USDOE, Washington, DC (United States)1997
Los Alamos National Lab., NM (United States). Funding organisation: USDOE, Washington, DC (United States)1997
AbstractAbstract
[en] Beryllium is difficult to weld because it is highly susceptible to cracking. The most commonly used filler metal in beryllium welds is Al-12 wt.% Si. Beryllium has been successfully welded using Al-Si filler metal with more than 30 wt.% Al. This filler creates an aluminum-rich fusion zone with a low melting point that tends to backfill cracks. Drawbacks to adding a filler metal include a reduction in service temperature, a lowering of the tensile strength of the weld, and the possibility for galvanic corrosion to occur at the weld. To evaluate the degree of interaction between Be and Al-Si in an actual weld, sections from a mock beryllium weldment were exposed to 0.1 M Cl- solution. Results indicate that the galvanic couple between Be and the Al-Si weld material results in the cathodic protection of the weld and of the anodic dissolution of the bulk Be material. While the cathodic protection of Al is generally inefficient, the high anodic dissolution rate of the bulk Be during pitting corrosion combined with the insulating properties of the Be oxide afford some protection of the Al-Si weld material. Although dissolution of the Be precipitate in the weld material does occur, no corrosion of the Al-Si matrix was observed
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1997; 6 p; 21. aging, compatibility, and stockpile stewardship conference; Albuquerque, NM (United States); 30 Sep - 2 Oct 1997; CONF-970982--; CONTRACT W-7405-ENG-36; ALSO AVAILABLE FROM OSTI AS DE98001312; NTIS; INIS; US GOVT. PRINTING OFFICE DEP
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