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AbstractAbstract
[en] Corrosion life of copper overpack is estimated on the basis of current understandings of copper corrosion processes. The assessment is based on the mass balance. Oxygen and sulfide were taken into account as corrosive species. The sulfate existing in bentonite is assumed to be reduced to sulfide by sulfate reducing bacteria and corrodes copper overpacks. Pitting is involved in the assesment using two methods. One method is use of pitting factor acquired from analysis of archeological artifacts. The other is use of extreme value statistical technique. The time evolution of parameters for cumulative probability distribution function, Gumbel distribution, was estimated using the data from copper specimens buried in various soil and archeological artifacts of the bronze age. The pitting depth for 1000 years is estimated using the parameters for probability distribution function. The result of estimation shows 39-mm is the maximum penetration for 1000 years. Natural analogue data suggest the corrosion rate of 3 mm/1000 years. Therefore the estimation is considered to be conservative. (author)
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Aug 1999; 19 p; Available from JICST Library (JICST: Japan Science and Technology Corporation, Information Center for Science and Technology), P.O. Box 10 Hikarigaoka, Tokyo 179-9810 Japan, FAX: +81-3-3979-2210, JICST Service Homepage: www.jst.go.jp/EN/JICST/ServiceGuide; 13 refs., 3 figs., 4 tabs.
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