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Kjoerk, Anders; Herstad Swaerd, Solvie
Vaermeforsk, Stockholm (Sweden)2000
Vaermeforsk, Stockholm (Sweden)2000
AbstractAbstract
[en] Recovery boiler NOx emissions are low compared with those from power boilers. However tighter environmental requirements to decrease the acidic emissions implies that all sources have to be addressed. There are an ongoing evaluation and development of NOx control technologies in the pulp industry. Basically air staging, selective catalytic reduction, SCR, and selective noncatalytic reduction, SNCR, have been discussed. Other NOx control options may be available as a result of ongoing research and development. As a background in the work to reduce the acid rain it has been considered necessary to have a good picture of the NOx emission from recovery boilers, and the Thermal Engineering Research Institute in Sweden have therefore sponsored this study. The intention is to give a good general view and try to explain the reasons for the large differences between boilers. Data from the 30 kraft recovery boilers which were in operation in Sweden during 1999 have been collected. Both NOx levels and specific conditions which could have an influence on the level have been included. The evaluation show a clear correlation between the nitrogen content in the liquor and the NOx level. It seams also that a long retention time in the furnace give an opportunity to reduce the amount of nitrogen oxide. For most boilers in Sweden the NOx levels are reported in mg/MJ and comparison could be done between different types of boilers. However for recovery boilers there could be a large uncertainty in the calculation which gives the amount (mg) of NOx, the definition of the heat input to be used (MJ) is either not clear. As a base for the study the measured concentration in ppm is used instead. The reported values are in the range of 30 - 100 ppm, however the majority of the boilers operate in a more narrow range 60-80 ppm. Air staging and other combustion methods could not reasonably reduce the NOx emission with more than 20% in the next decade. If the goal is higher other methods must be considered and the options today is SCR or SNCR. Both these secondary methods of reducing NOx has drawbacks: there is a safety risk if SNCR is used and SCR is not proven and development work will be required
Original Title
Kartlaeggning av NOx-utslaepp fraan sodapannor i Sverige
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May 2000; 58 p; ISSN 0282-3772;
; PROJECT VAERMEFORSK-S9-807; Available from Vaermeforsk Service AB, SE-101 53 Stockholm, Sweden; OSTI; Available to ETDE participating countries only(see www.etde.org); commercial reproduction prohibited; OSTI as DE20086729; PURL: https://www.osti.gov/servlets/purl/20086729-htmXid/webviewable/; Figures and tables with text in English. 34 refs, 15 figs, 10 tabs

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