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AbstractAbstract
[en] The pressure behavior of the phonon modes of tetragonal two-dimensional polymeric C60 has been studied at pressure up to 27.5 GPa and room temperature by means of Raman spectroscopy. Gradual transformation of the material to a new phase was observed in the pressure region 18.0-22.0 GPa. The Raman spectrum characteristics of the high-pressure phase provide a strong indication that the fullerene molecular cage is retained and the material may be related to a three-dimensionally polymerized C60. The new phase remains stable upon pressure decrease down to 9 GPa. Further release of pressure leads to its transformation to a highly disordered structure whose broad features in the Raman spectrum resemble those of amorphous carbon. (orig.)
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HPSP 2000: 9. international conference on high pressure semiconductor physics; Sapporo (Japan); 24-28 Sep 2000; 16 refs.; Proceedings. Pt. 2
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Journal Article
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