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AbstractAbstract
[en] Melt-textured YBa2Cu3O7-y (Y123) containing fine particles of Y2BaCuO5 (Y211) has been prepared from Y123/Y211 powder that was attrition milled with 1 wt% CeO2 addition, and the microstructure has been examined. Fine and spherical Y211 particles (less than 1 μm in size) are found to be homogeneously dispersed within the melt-textured Y123 domain. Many dislocations are observed to be formed around the trapped Y211 and the Ba(Ce, Zr)O3 inclusions, which were formed as a result of CeO2 addition and ZrO2 introduction from the jar and ball used for attrition milling. CuO stacking faults were also observed around the trapped Y211; these were initiated at the Y123/Y211 interface and extended into the Y123 matrix. Each stacking fault has a lenticular shape, with a width of a few tens of nanometres and a length of a few hundred nanometres, and the faults developed along the [100] and [010] directions of the Y123. The formation mechanism of the stacking fault was discussed together with the formation of the platelet structure (the elongated Ba-Cu-O phase) on the basis of an oxygenation-induced decomposition of the Y123 phase. It is concluded that the prolonged oxygenation heat treatment producing the tetragonal-to-orthorhombic phase transformation is responsible for the formation of the platelet structure and possibly for the formation of the stacking faults. (author)
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Source
Available online at the Web site for the journal Superconductor Science and Technology (ISSN 1361-6668) http://www.iop.org/; Country of input: Peru
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Journal Article
Journal
Superconductor Science and Technology; ISSN 0953-2048;
; v. 9(2); p. 76-87

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ALKALINE EARTH METAL COMPOUNDS, BARIUM COMPOUNDS, CERIUM COMPOUNDS, CHALCOGENIDES, COPPER COMPOUNDS, CRYSTAL DEFECTS, CRYSTAL STRUCTURE, MACHINING, OXIDES, OXYGEN COMPOUNDS, PHASE TRANSFORMATIONS, RARE EARTH COMPOUNDS, SUPERCONDUCTORS, TRANSITION ELEMENT COMPOUNDS, TYPE-II SUPERCONDUCTORS, YTTRIUM COMPOUNDS, ZIRCONIUM COMPOUNDS
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