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AbstractAbstract
[en] The lattice instability related to ferroelectric phase transitions of SrBi2Ta2O9 and its family has been studied by Raman scattering in the temperature range between 293 K and 958 K. The lowest optical mode of SrBi2Ta2O9 of 29 cm-1 at room temperature shows remarkable temperature variation towards TC=608 K. Its mode frequency decreases markedly and the damping factor increases rapidly below TC. The composition dependence of the low-frequency modes has been investigated in the family ABi2M2O9 (A=Ba, Ca, Sr, M=Nb, Ta) and Bi3TiMO9 (M=Nb, Ta). All the lowest modes soften upon heating, except BaBi2M2O9 (M=Nb, Ta). The nature of the damping of the soft modes is discussed in relation to the ionic radius of the A site of a pseudo-perovskite unit. (author). Letter-to-the-editor
Source
Available online at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: Belarus; 20 refs
Record Type
Journal Article
Journal
Journal of Physics. Condensed Matter; ISSN 0953-8984;
; v. 10(20); p. L327-L332

Country of publication
BARIUM COMPOUNDS, BCS THEORY, BISMUTH COMPOUNDS, BISMUTH OXIDES, CALCIUM COMPOUNDS, CRITICAL TEMPERATURE, FERROELECTRIC MATERIALS, FREQUENCY DEPENDENCE, LATTICE PARAMETERS, LAYERS, NIOBIUM COMPOUNDS, OPTICAL MODES, OXYGEN COMPOUNDS, PEROVSKITE, PHASE TRANSFORMATIONS, RAMAN EFFECT, STRONTIUM COMPOUNDS, SUPERCONDUCTIVITY, TANTALUM COMPOUNDS, TEMPERATURE DEPENDENCE, TEMPERATURE RANGE 0273-0400 K, TEMPERATURE RANGE 0400-1000 K
ALKALINE EARTH METAL COMPOUNDS, BISMUTH COMPOUNDS, CHALCOGENIDES, DIELECTRIC MATERIALS, ELECTRIC CONDUCTIVITY, ELECTRICAL PROPERTIES, MATERIALS, MINERALS, OSCILLATION MODES, OXIDE MINERALS, OXIDES, OXYGEN COMPOUNDS, PEROVSKITES, PHYSICAL PROPERTIES, REFRACTORY METAL COMPOUNDS, TEMPERATURE RANGE, THERMODYNAMIC PROPERTIES, TRANSITION ELEMENT COMPOUNDS, TRANSITION TEMPERATURE
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