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AbstractAbstract
[en] We have measured the electronic resistivity and thermopower of liquid Cu1-cCec, Cu1-cLac, and Ag1-cCec alloys for c < 0.4. In all of the alloys the resistivity is very similar, rising smoothly and steeply as c increases, but at all times remaining less than 200 μΩ cm. The thermopower is also featureless and metallic. However, the temperature coefficient, α=(1/ρ)dρ/d t, displays in the Cu alloys a minimum for Cu6 R E (R E = rare earth), which furthermore is negative for Cu6Ce; a negative temperature coefficient is also seen for Ag3Ce. We also present the results of an investigation of neutron diffraction scattering from liquid Cu6Ce, and the results of a reverse Monte Carlo (RMC) analysis of the structure data, which shows evidence of ordering in the liquid, with characteristics similar to those of crystalline Cu6Ce. We discuss several possible explanations for the negative temperature coefficient of both Ag and Cu alloys, and conclude that its origin lies in the presence of chemical short-range order. (author). Letter-to-the-editor
Source
Available online at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: Brazil; 15 refs
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Journal Article
Journal
Journal of Physics. Condensed Matter; ISSN 0953-8984;
; v. 9(50); p. L677-L685

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