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AbstractAbstract
[en] The ferroelastic and antiferroelectric transition (between phases called P and R) in NaNbO3 samples, pure and doped with Mn (0-3.3 mol %), was investigated. The phase diagram was obtained from DTA tests. The doping resulted in lowering of the P-R phase transition temperature. The shift of the P-R phase transition temperature was observed also in dielectric permittivity ε(T) measured under compression. Changes in enthalpies obtained from DTA were compared to the latent heat values calculated independently from the Clapeyron - Clausius equation. Values of thermodynamic parameters of the P-R phase transition were evaluated. The EPR test showed that the Mn dopant causes disorder and local strains. Athermal martensitic behaviour of the P-R phase transition in NaNbO3 was enhanced by applied compression and the dopant subsystem. (author)
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Source
Available online at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: Brazil
Record Type
Journal Article
Journal
Journal of Physics. Condensed Matter; ISSN 0953-8984;
; v. 9(50); p. 11263-11282

Country of publication
ALKALI METAL COMPOUNDS, ALLOYS, CARBON ADDITIONS, DIAGRAMS, DIELECTRIC MATERIALS, INFORMATION, IRON ALLOYS, MANGANESE ALLOYS, MATERIALS, NIOBIUM COMPOUNDS, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, REFRACTORY METAL COMPOUNDS, THERMODYNAMIC PROPERTIES, TRANSITION ELEMENT ALLOYS, TRANSITION ELEMENT COMPOUNDS
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