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AbstractAbstract
[en] Raman scattering investigations were performed over a large temperature range from 10 to 700 K on pure and Ti-doped PbHfO3 single crystals. The modifications of the Raman spectra were precisely observed in the vicinity of two structural phase transitions occurring in the crystal: an antiferroelectric (A1) to antiferroelectric (A2) phase transition at 436 K and antiferroelectric (A2) to paraelectric (P) phase transition at 484 K. The characteristic parameters of the Raman structures were determined throughout the whole phase transition sequence. The softening of the two lowest-frequency Raman lines seems to have a dominating influence on the slight increase in dielectric permittivity at the A1 to A2 phase transition in both pure and doped samples suggesting a displacive nature for this transition. For Ti-doped samples the form of the A1 to A2 transition is smoother than for undoped samples while the A1 to P transition appears to be unaffected by doping with Ti. (author)
Source
Available online at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: Uzbekistan
Record Type
Journal Article
Journal
Journal of Physics. Condensed Matter; ISSN 0953-8984;
; v. 7(20); p. 3957-3972

Country of publication
ALLOYS, DIELECTRIC MATERIALS, DIELECTRIC PROPERTIES, ELECTRICAL PROPERTIES, HAFNIUM COMPOUNDS, LASER SPECTROSCOPY, MATERIALS, OXYGEN COMPOUNDS, PHASE TRANSFORMATIONS, PHYSICAL PROPERTIES, REFRACTORY METAL COMPOUNDS, SPECTRA, SPECTROSCOPY, TITANIUM ALLOYS, TRANSITION ELEMENT ALLOYS, TRANSITION ELEMENT COMPOUNDS
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