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AbstractAbstract
[en] The single-phase compounds of R2Fe17-xAlxC (x=0-8; R≡Ho, Y or Sm) were fabricated by arc melting. Their structural and magnetic properties have been investigated by means of X-ray diffraction and magnetization measurements. X-ray diffraction patterns demonstrate that all compounds have a single phase with a hexagonal Th2Ni17-type or a rhombohedral Th2Zn17-type structure. The substitution of Al atoms leads to increase in the lattice constants and the unit-cell volume. The Curie temperature is found to change slightly when x≤3 and then to decrease rapidly with increasing Al concentration. An approximately linear decrease in the saturation magnetization with increasing x is observed by the substitution of non-magnetic Al atoms. The compensation points are observed for the Ho2Fe17-xAlxC samples with x≥5. Samples of Sm2Fe17-xAlxC with x≤6 exhibit an easy c-axis anisotropy at room temperature. The room-temperature anisotropy field increases to about 119 kOe when x=2 and then decreases with increasing Al concentration. The substitution of Al for Fe in a small concentration will increase the anisotropy field of Sm2Fe17 carbides. This behaviour is the same as that of Ga and Si. (author)
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Available online at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: Uzbekistan
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Journal Article
Journal
Journal of Physics. Condensed Matter; ISSN 0953-8984;
; v. 7(17); p. 3195-3202

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