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AbstractAbstract
[en] D-Glucose, sucrose and triphenylmethylcarbinol dithiocarbonate complexes of molybdenum(V), [Mo2OS3(glu-2CS2)].2H2O, [Mo2S4(suc-4CS2)].2H2O, and [Mo2OS3(Ph3COCS2)2].2H2O, respectively have been synthesized. The compositions are strongly influenced by the nature of xanthates and the experimental conditions of preparation. The TG-DTA data suggest the presence of lattice water. On the basis of magnetic moment and spectroscopic data, oxo or sulphido bridged structures are suggested for the molybdenum compounds. (author)
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20 refs., 1 fig., 1 tab.
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Journal Article
Journal
Indian Journal of Chemistry. Section A: Inorganic, Bio-inorganic, Physical, Theoretical and Analytical Chemistry; CODEN ICACEC; v. 39(10); p. 1083-1086
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