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Mangala, M.J.; Korir, K.A.; Maina, D.M.; Kinyua, A.M., E-mail: mmangala@insightkenya.com
8. conference on total reflection x-ray fluorescence analysis and related methods2000
8. conference on total reflection x-ray fluorescence analysis and related methods2000
AbstractAbstract
[en] Results of trace element analysis by TXRF of tap water and various brands of bottled mineral water samples which are representative of local and imported brands sold in Nairobi are reported. The variation in elemental concentrations in water samples analyzed were as follows: potassium (K) 0.2 to 28.9 μg/ml; calcium (Ca) 2.2 to 120 μg/ml; titanium (Ti) 11 to 60 μg/l; manganese (Mn) 8 to 670 μg/l; iron (Fe) 31 to 540 μg/l; copper (Cu) 8 to 30 μg/l; zinc (Zn) 8 to 4730 μg/l; bromine (Br) 9 to 248 μg/l; rubidium (Rb) 10 to 40 μg/l and strontium (Sr) 10 to 1000 μg/l. Local mineral water samples contain higher levels of trace elements; manganese (Mn), zinc (Zn), bromine (Br), rubidium (Rb) and strontium (Sr) as compared to the imported brands. Principal component analysis of the results revealed three component loading factors clusters for: rubidium (Rb), strontium (Sr) and calcium (Ca); titanium (Ti), iron (Fe), bromine (Br), and zinc (Zn); zinc (Zn), manganese (Mn) and potassium (K) respectively. The percentage of total variance explained by the components was 31.4, 27.3, and 14.8 respectively. In this study, we also found that a limited spread of 5-6 mm for a 10 μl sample was achieved when the quartz sample carrier was dried in a low pressure (300 mbar) oven at 70 oC for 10 hours. (author)
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Wobrauschek, P. (ed.) (Atominstitut, Stadionallee 2, 1020 Vienna (Austria)); Atominstitut der oesterreichischen Universitaeten, Technische Universitaet Wien, Stadionallee 2, 1020 Vienna (Austria). Funding organisation: Amptek Inc. 6, De Angelo Drive, Bedford (United States); Atomika, Atomika Instruments GmbH, Bruckmannring 40, D-85764 Oberschleissheim (Germany); Brau AG (Austria); Coca-Cola Beverages Austria (Austria); Creditanstalt (Austria); Intax, Schwarzschildstrasse 10, D-1248 Ital Structures (Germany); Pfeiffer Vacuum Austria, Diefenbachgasse 35, A-1150 Wien (Austria); Philips Analytical, Lelyweg 1, 7602 EA Almelo (Netherlands); Stadt Wien, Vienna (Austria); Technos (Japan); TU Wien, Vienna (Austria); et al; 108 p; 2000; p. 81; 8. conference on total reflection x-ray fluorescence analysis and related methods; Vienna (Austria); 25-29 Sep 2000; Available in abstract form only, full text entered in this record. Also available from Atominstitut der oesterreichischen Universitaeten, Technische Universitaet Wien, Stadionallee 2, 1020 Vienna (AT). e-mail: wobi@ati.ac.at
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