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Carlson, C.D.; Delegard, C.H.; Burgeson, I.E.; Schmidt, A.J.; Bredt, P.R.; Silvers, K.L.
Pacific Northwest National Lab., Richland, WA (United States). Funding organisation: US Department of Energy (United States)1998
Pacific Northwest National Lab., Richland, WA (United States). Funding organisation: US Department of Energy (United States)1998
AbstractAbstract
[en] This report describes tests performed by Pacific Northwest National Laboratory (PNNL) for Numatec Hanford Corporation (NHC) as part of the overall activities for the development of the K Basin Sludge Treatment System. These tests were conducted to examine the dissolution behavior of a K East Basin canister sludge composite in nitric acid at the following concentrations: 2 M, 4 M, 6 M, 7.8 M and 10 M and temperatures of 25 C and boiling. Assuming that the sludge was 100% uranium metal, a 4X stoichiometric excess of nitric acid was used for all testing, except that conducted at 4 M. In the 4 M nitric acid dissolution test, 50% excess nitric acid was used resulting in a dissolver solution with a significantly higher solids loading. The boiling tests were conducted for 11 hr, the 25 C dissolution tests were conducted from 24 hr to 2 weeks. For the 25 C dissolution testing, the weight percent residual solids was determined, however, chemical and radiochemical analyses were not performed
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24 Jul 1998; 33 p; AC06-76RL01830; Also available from OSTI as DE00005088; PURL: https://www.osti.gov/servlets/purl/5088-IzqdmS/webviewable/
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