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Morita, Y.; Yamaguchi, I.; Fujiwara, T.; Koizumi, H.; Tachimori, S.
Scientific research on the back-end of the fuel cycle for the 21. century2000
Scientific research on the back-end of the fuel cycle for the 21. century2000
AbstractAbstract
[en] The demonstration test of 4-Group Partitioning Process with concentrated real high-level liquid waste (HLLW) was carried out in the Partitioning Test Facility installed in a hot cell. More than 99.998% of Am and Cm were extracted from the HLLW with the organic solvent containing 0.5 M DIDPA - 0.1 M TBP, and more than 99.98% of Am and Cm were back-extracted with 4 M nitric acid. Np and Pu were extracted simultaneously, and more than 99.93% of Np and more than 99.98% of Pu were back-extracted with oxalic acid. In the denitration step for the separation of Tc and platinum group metals, more than 90% of Rh and more than 97% of Pd were precipitated. About half of Ru were remained in the de-nitrated solution, but the remaining Ru were quantitatively precipitated by neutralization of the de-nitrated solution to pH 6.7. In the adsorption step, both Sr and Cs were separated effectively. Decontamination factors for Cs and Sr were more than 106 and 104 respectively in all effluent samples. (authors)
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CEA/VALRHO - site de Marcoule, Dept. de Recherche en Retraitement et en Vitrification (DRRV), 30 - Marcoule (France); [575 p.]; 2000; p. 1-4; International conference Scientific research on the back-end of the fuel cycle for the 21. century. Atalante 2000; Avignon (France); 24-26 Oct 2000; 10 refs.
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