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AbstractAbstract
[en] The quasi-elastic cold neutron incoherent scattering law, QNS, for the assumed case of transversal standing wave type of motion of the linear chain a spacer-of the polyacrylate polymer liquid crystal, based upon the random walk of the particle between two perfectly potential barriers, is derived. The spacer protons are taken to vibrate (within the stationary plane) transversely to the line joining the oxygen atoms in a way where they are all simultaneously displaced in the same direction with amplitudes of the standing wave fundamental mode of the vibration excited. The calculated relevant incoherent scattering law is found to be a non-distinct function of the scattering vector Q, in the sense that the postulated dynamical effect of the spacer protons causes the peak value of the calculated incoherent scattering law, S(Q,ω), to remain constant throughout the experimentally accessible range of the scattering vector Q. It appears that, when the experimental resolution broadening effects is taken into account, the contribution of the postulated dynamical behavior to the measured QNS spectra might be small, particularly so, if dome additional motion of the scatters is present, and consequently the standing wave like spacer dynamics in polymer liquid crystals will be very difficult to be identified uniquely in the quasielastic neutron scattering experiments.(author)
Source
Ravnik, M.; Jencic, I.; Zagar, T. (Nuclear Society of Slovenia, Ljubljana (Slovenia)) (eds.); Nuclear Society of Slovenia, Ljubljana (Slovenia). Funding organisation: European Nuclear Society (Switzerland); Nuclear Power Plant Krsko (Slovenia); Siemens Power Generation Group, Erlangen (Germany); Ministry of Science and Technology of Slovenia, Ljubljana (Slovenia); Institute Jozef Stefan (Slovenia); American Society of Mechanical Engineers (United States); ENCONET Consulting GmbH (Austria); SIAP d.o.o. Pesnica pri Mariboru (Slovenia); Institute for Metal Constructions (Slovenia); Agency for Radwaste management (Slovenia); Slovenian Nuclear Safety Administration (Slovenia); 519 p; ISBN 961-6027-10-5;
; 1998; p. 83-90; Nuclear Society of Slovenia; Ljubljana (Slovenia); Nuclear Energy in Central Europe 98; Terme Catez (Slovenia); 7-10 Sep 1998; Also available from Nuclear Society of Slovenia, Jozef Stefan Institute, Jamova 39, Ljubljana (SI); 9 refs., 4 figs.

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