[en] This paper introduces a thermodynamic model to determine composition, temperature and pressure of the plasma cloud induced by pulsed laser irradiation in the case where a relevant thermal sputtering mechanism is operating at the surface of a molten layer. The model concerns in particular pulse lengths of the order of several nanoseconds and completes the results of a previous paper concerning the physics of the evaporation and boiling driven thermal sputtering (Tosto S 2002 J. Phys. D: Appl. Phys. 35); the recession rate and temperature at the molten surface are linked to the pulse fluence and plasma properties in the frame of a unique physical model. This paper shows that the plasma properties depend critically on the non-equilibrium character of the surface evaporation and boiling mechanisms. The extension of the model to the case of continuous laser irradiation is also discussed. Some examples of computer simulation aim to show the results available in the particular case of a metal target; the comparison between calculated and experimental data supports the validity of the model