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Balbaud-Celerier, F.; Deloffre, P.; Terlain, A.; Rusanov, A.
Structural materials for hybrid systems: a challenge in metallurgy2002
Structural materials for hybrid systems: a challenge in metallurgy2002
AbstractAbstract
[en] Corrosion tests of martensitic and austenitic steels were performed in a forced liquid eutectic Pb-Bi circulation loop. Experiments were carried out at 470 deg C and 600 deg C. Two oxygen concentrations in Pb-Bi were studied: 10-6 wt % and 10-7-10-8 wt %. The results showed that at 470 deg C, all the tested steels have a satisfying corrosion behaviour for both oxygen contents. An oxide layer is formed on martensitic steels (T91 and EM10); its thickness depends on the oxygen content. It is constituted of an outer layer of magnetite and an inner (Fe, Cr)3O4 spinel layer. Austenitic steel 316L is protected by a very thin oxide layer (< 1 μm). At 600 deg C, martensitic steels (T91 and EM10) undergo an important oxidation for both oxygen contents (after 1000h, the thickness of the oxide layer varies from 10-15 μm to 20-25 μm depending on the oxygen content). The oxide layer is constituted of (Fe, Cr)3O4 spinel and appears porous. Austenitic 316L undergoes severe dissolution at the lowest oxygen content in Pb-Bi and partial dissolution and oxidation at the highest oxygen concentration. Erosion phenomena were observed on all the steels. (authors)
Original Title
Corrosion de materiaux metalliques dans l'alliage Pb-Bi
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Source
Gorce, D. (Centre National de la Recherche Scientifique (CNRS), 94 - Vitry-sur-Seine (France)); Boutard, J.L. (CEA Sacaly, Dir. de la Simulation et des Outils Experimentaux - DSOE, 91 - Gif sur Yvette (France)); 305 p; ISBN 2-86883-617-8;
; Sep 2002; p. 177-190; Symposium on ''Structural materials for hybrid systems: a challenge in metallurgy''; Paris (France); 29-31 Oct 2001; 14 refs.

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