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AbstractAbstract
[en] Electron paramagnetic resonance (EPR) and electron-nuclear double resonance have been used to characterize the neutral copper acceptor in ZnGeP2 crystals. The copper substitutes for zinc and behaves as a conventional acceptor (i.e. the 3d electrons do not play a dominant role). Because of a high degree of compensation from native donors, the copper acceptors in our samples were initially in the nonparamagnetic singly ionized state (CuZn-). The paramagnetic neutral state (CuZn0) was observed when the crystals were exposed to 632.8 nm or 1064 nm laser light while being held at a temperature below 50 K. The g matrix of the neutral copper acceptor is axial gpar = 2.049 and gperp = 2.030), with the unique principal direction parallel to the tetragonal c axis of the crystal. The hyperfine and nuclear quadrupole matrices also exhibit c-axis symmetry (Apar = 87.6 MHz, Aperp = 34.8 MHz and P = 0.87 MHz for 63Cu and Apar = 93.9 MHz, Aperp = 37.3 MHz and P = 0.81 MHz for 65Cu). Equal hyperfine interactions with the four nearest-neighbour phosphorus ions are well resolved in the c-axis EPR spectrum
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S0953-8984(03)52299-8; Available online at http://stacks.iop.org/0953-8984/15/1625/c31011.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: International Atomic Energy Agency (IAEA)
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