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Wang, Y; Mitkova, M; Georgiev, D G; Mamedov, S; Boolchand, P
Center for Solid State Electronics Research, Arizona State University, Tempe, AZ 85287-6206 (United States)2003
Center for Solid State Electronics Research, Arizona State University, Tempe, AZ 85287-6206 (United States)2003
AbstractAbstract
[en] Temperature modulated differential scanning calorimetry measurements on Agy(GexSe1-x)1-y glasses provide evidence for bimodal glass transition temperatures in Se-rich glasses (x < 1/3). At x = 0.20 and 0.25, thermal measurements performed as a function of Ag content in the 0 ≤ y ≤ 0.25 range reveal that the additive (Ag) segregates into an Ag2Se-rich glass phase, possessing a characteristic glass transition temperature Tga 230 deg. C, while the remaining base glass displays a second glass transition temperature Tgb that systematically increases as its Se content is depleted. The present thermal results are in harmony with Raman scattering, neutron diffraction, dielectric spectroscopy and optical microscopy measurements and suggest that Se-rich glasses in the Ag-Ge-Se ternary system intrinsically phase separate on a macroscopic scale
Source
CECAM workshop on atomic structure and transport in glassy networks; Lyon (France); 24-26 Jun 2002; S0953-8984(03)56000-3; Available online at http://stacks.iop.org/0953-8984/15/S1573/c31607.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: International Atomic Energy Agency (IAEA)
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