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AbstractAbstract
[en] We investigate the structure and dynamics of ionic magnetic fluids (MFs), based on ferrite nanoparticles, dispersed at pH ∼ 7 either in H2O or in D2 O. Polarized and non-polarized static small angle neutron scattering (SANS) experiments in zero magnetic field allow us to study both the magnetic and the nuclear contributions to the neutron scattering. The magnetic interparticle attraction is probed separately from the global thermodynamic repulsion and compares well to direct magnetic susceptibility measurements. The magnetic interparticle correlation is in these fluid samples independent of the probed spatial scale. In contrast, a spatial dependence of the interparticle correlation is evidenced at large Φ by the nuclear structure factor. A model of magnetic interaction quantitatively explains the under-field anisotropy of the SANS nuclear contribution. In a quasi-elastic neutron spin-echo experiment, we probe the Brownian dynamics of translation of the nanoparticles in the range 1.3 ≤ qRgN≤ 10 (q, scattering vector; RgN, nuclear radius of gyration of the nanoparticles). For the first time in an MF, we determine the hydrodynamic function at large q vectors
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S0953-8984(03)54824-X; Available online at http://stacks.iop.org/0953-8984/15/S1305/c31502.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: International Atomic Energy Agency (IAEA)
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