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AbstractAbstract
[en] Sharp absorption lines produced by hydrogen in diamond have been studied in diamonds grown from 13C by high-pressure, high-temperature synthesis. Analyses of the two-phonon intrinsic absorption and of the Raman shift have shown that the 12C content of the diamond is 13.5%. This value is entirely consistent with the relative intensities of the absorption lines at 3107 and 3098 cm-1, confirming that they are due to a strongly localized C-H stretching vibration. A correlated line, observed at 1405 cm-1 for natural diamond, and attributed to the C-H bending vibration, exhibits both an isotope shift and a shift due to weak coupling with the one-phonon modes. By analogy with natural diamond, lines for the 13C diamond at 2757 and 4469 cm-1 are assigned to the combinations 2 h-bar ωb and h-bar ωs + h-bar ωb, respectively, where h-bar ωs and h-bar ωb are the stretch and bend frequencies. The frequency invariance, on carbon isotope substitution, of a hydrogen-related line at 3237 cm-1 is not inconsistent with the proposal that this is produced by a N-H vibration
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S0953-8984(03)60544-8; Available online at http://stacks.iop.org/0953-8984/15/3163/c31916.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: International Atomic Energy Agency (IAEA)
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