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AbstractAbstract
[en] The formation, crystal structure and magnetic properties of Sm2Fe17-xCoxCy were studied. The substitution of Co for Fe helps to stabilize the rhombohedral Th2Zn17-type structure (2:17) and eliminate α-Fe formation for carbon concentrations y ≤ 1.5. From the mixing enthalpy calculations based on Miedema's semi-empirical model and Wigner-Seitz cell analysis, it is found that the role of Co in stabilizing the 2:17 structure is related to its strong preference for the 18h site, which has a maximum number of rare-earth near neighbours in the structure. With increasing Co content, x, the lattice constants decrease while the Curie temperature rapidly increases. The typical compound Sm2Fe12Co5C1.25 has a room temperature saturation magnetization μ0Ms = 1.36 T, a magnetic anisotropy field μ0Hk = 7.1 T, a Curie temperature TC = 874 K and a possible maximum operating temperature Tm higher than 473 K
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S0953-8984(03)59179-2; Available online at http://stacks.iop.org/0953-8984/15/3315/c31930.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: International Atomic Energy Agency (IAEA)
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