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AbstractAbstract
[en] The problem of isomorphism in phosphates that are structural analogues of mineral kosnarite (structural type of sodium zirconium orthophosphate NaZr2(PO4)3, NZP), monazite, and others, are discussed. Data on the crystal chemistry of orthophosphates of the framework structure are systematised according to the suggested classification of their formula types. The theoretically expected solid solutions and the realised ones are viewed. Especially isomorphism of f-elements in various structures of phosphates is presented. These data form the basis on monophase ceramics that can be easily adapted to many kinds of nuclear waste compositions. (author)
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Source
14. radiochemical conference; Marianske Lazne (Czech Republic); 14-19 Apr 2002; RFBR GRANTS 02-03-32181; 01-03-33013; 1 tab., 3 figs., 10 refs.
Record Type
Journal Article
Literature Type
Conference
Journal
Czechoslovak Journal of Physics; ISSN 0011-4626;
; v. 53(suppl.A,pt.2); p. A649-A655

Country of publication
ALKALI METAL COMPOUNDS, DISPERSIONS, ELEMENTS, HOMOGENEOUS MIXTURES, MANAGEMENT, MATERIALS, METALS, MINERALS, MIXTURES, OXYGEN COMPOUNDS, PHASE TRANSFORMATIONS, PHOSPHATE MINERALS, PHOSPHATES, PHOSPHORUS COMPOUNDS, PROCESSING, RADIOACTIVE MATERIALS, RADIOACTIVE MINERALS, RADIOACTIVE WASTE MANAGEMENT, SODIUM COMPOUNDS, SOLUTIONS, THORIUM MINERALS, TRANSITION ELEMENT COMPOUNDS, WASTE MANAGEMENT, WASTE PROCESSING, ZIRCONIUM COMPOUNDS
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