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AbstractAbstract
[en] The technique of Translational Energy Spectrometry (TES) has been used to study electron capture processes for a number of ion-atom and ion-molecule collision systems at energies < 1 keV/amu. The systems studied were: He2+ ions in H2 and CO; helium-like C4+, N5+ and O6+ ions in H and H2; and hydrogen-like C5+, N6+, and O7+ ions in H and H2. For each system, the main reaction channels have been identified, and in most cases, their relative importance assessed. For He2+ ions in H2 and CO, dissociative one-electron capture processes have been found to account for almost 100% of the total one-electron capture cross at low energies. Dissociative one-electron capture processes were also observed in the C5++H2 and O7++H2 systems. However, in the case of N5++H2, two electron capture into autoionising states of N3+ with subsequent N4+(n=2) formation was found to be an important process at low energies, accounting for approximately 50% of the total electron capture cross section at 214 eV/amu. Dissociative capture processes were not found to be important for C4+, N6+, and O6+ systems. In the case of electron capture from an atomic hydrogen target, capture was found to occur predominantly into n=4 levels for the N5+, N6+, C5+, and O6++H systems. For the C4++H system, C3+(n=3) formation was found to be the dominant reaction channel, with O6+(n=5) formation the favoured reaction channel in the O7++H system. Total charge-changing cross sections have also measured for the N5++H2 system using a simple beam attenuation method. While agreeing with previous PES measurements in the region of overlap, the measurements are in poor agreement with OPIG measurements and theoretical calculations. For some of the systems studied, Landau-Zener and classical over-barrier reaction-windows have been calculated. For N5+, O5+, and C3+ ions colliding with H and H2, agreement with the present results was found to be good
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Source
2002; [np]; Queen's University of Belfast; Belfast (United Kingdom); Available from British Library Document Supply Centre- DSC:DXN060082; Country of input: International Atomic Energy Agency (IAEA); Thesis (Ph.D.)
Record Type
Miscellaneous
Literature Type
Thesis/Dissertation
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