Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.017 seconds
AbstractAbstract
[en] Superconductivity in the copper oxides occurs at a crossover from localized to itinerant electronic behaviour, a transition that is first order. A spinodal phase segregation is normally accomplished by atomic diffusion; but where it occurs at too low a temperature for atomic diffusion, it may be realized by cooperative atomic displacements. Locally cooperative, fluctuating atomic displacements may stabilize a distinguishable phase lying between a localized-electron phase and a Fermi-liquid phase; this intermediate phase exhibits quantum-critical-point behaviour with strong electron-lattice interactions making charge transport vibronic. Ordering of the bond-length fluctuations at lower temperatures would normally stabilize a charge-density wave (CDW), which suppresses superconductivity. It is argued that in the copper oxide superconductors, crossover occurs at an optimal doping concentration for the formation of ordered two-electron/two-hole bosonic bags of spin S = 0 in a matrix of localized spins; the correlation bags contain two holes in a linear cluster of four copper centres ordered within alternate Cu-O-Cu rows of a CuO2 sheet. This ordering is optimal at a hole concentration per Cu atom of p ∼ 1/6, but it is not static. Hybridization of the vibronic electrons with the phonons that define long-range order of the fluctuating (Cu-O) bond lengths creates barely itinerant, vibronic quasiparticles of heavy mass. The heavy itinerant vibrons form Cooper pairs having a coherence length of the dimension of the bosonic bags. It is the hybridization of electrons and phonons that, it is suggested, stabilizes the superconductive state relative to a CDW state. (topical review)
Source
S0953-8984(03)31434-1; Available online at http://stacks.iop.org/0953-8984/15/R257/c307r1.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Country of publication
ANGULAR MOMENTUM, CHALCOGENIDES, COPPER COMPOUNDS, CRYSTAL STRUCTURE, DIMENSIONS, ELEMENTARY PARTICLES, ENERGY LEVELS, EXCITED STATES, FERMIONS, LENGTH, LEPTONS, MATHEMATICAL MODELS, NUCLEAR MODELS, OXIDES, OXYGEN COMPOUNDS, PARTICLE PROPERTIES, PHASE TRANSFORMATIONS, PHYSICAL RADIATION EFFECTS, QUASI PARTICLES, RADIATION EFFECTS, TRANSITION ELEMENT COMPOUNDS, VARIATIONS
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue