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AbstractAbstract
[en] We have measured the 57Fe Moessbauer spectra of the Hofmann pyridine complex Fe(pyridine)2Ni(CN)4 sample before and after exposure to high pressure of gaseous xenon. The temperature dependence of the high spin molar fraction has been determined from the 57Fe Moessbauer spectra. The spin transition of the sample without the high pressure treatment occurs between 175 and 220 K with a hysteresis width of 15 K. Although the 57Fe Moessbauer spectra suggest that the spin crossover behavior of the sample before and after the high pressure treatment are almost the same, the hysteresis of the latter sample is somewhat larger. (author)
Source
Asia-Pacific Symposium on Radiochemistry. Part 3; Fukuoka (Japan); 30 Oct - 1 Nov 2001; 15 refs.
Record Type
Journal Article
Literature Type
Conference
Journal
Journal of Radioanalytical and Nuclear Chemistry; ISSN 0236-5731;
; CODEN JRNCDM; v. 255(3); p. 509-512

Country of publication
AZINES, COMPLEXES, ELEMENTS, ENERGY LEVELS, EVEN-ODD NUCLEI, FLUIDS, GASES, HETEROCYCLIC COMPOUNDS, INTERMEDIATE MASS NUCLEI, IRON ISOTOPES, ISOTOPES, NONMETALS, NUCLEI, ORGANIC COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, PYRIDINES, RARE GASES, STABLE ISOTOPES, TRANSITION ELEMENT COMPLEXES, TRANSITION ELEMENT COMPOUNDS
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