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AbstractAbstract
[en] Previous investigations showed that laser Raman spectroscopy (LRS) can be used as a phase specific analytical tool for radioactive fuel crud samples and also for details in the underlying layer of zirconium dioxide. It is relatively easy to record Raman spectra that discriminate between chemical phases for all crud oxides of interest. The method has therefore been recommended for crud investigations within the Swedish program. At ideal conditions the resolution is about 1 μm, permitting detailed position determination of crud phases in the sample. Therefore LRS is a very good complement to X-ray diffraction (XRD). The methods for sample preparation and handling of radioactive crud samples for LRS turn out to be relatively simple. A detailed LRS study on fuel crud samples from Barsebaeck 2, Forsmark 2, Forsmark 3 and Ringhals 1 was performed in this work. All of those Swedish BWRs were operated at different conditions at the time of sampling. The chemistry regimes covered NWC, HWC and other variable conditions. Also different types of fuel, exposure times and sampling positions were selected. (authors)
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2002; 13 p; Chemistry 2002: International conference on water chemistry in nuclear reactors systems - operation optimisation and new developments; Chimie 2002: La chimie de l'eau dans les reacteurs nucleaires - Optimisation de l'exploitation et developpements nouveaux; Avignon (France); 22-26 Apr 2002; Also available from SFEN-CHIMIE2002, 67, rue Blomet, 75015 Paris (France)
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Miscellaneous
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Conference
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CHALCOGENIDES, DEPOSITION, ELEMENTS, ENRICHED URANIUM REACTORS, FUEL ELEMENTS, HYDROGEN COMPOUNDS, HYDROXIDES, IRON COMPOUNDS, IRON ORES, LASER SPECTROSCOPY, METALS, MINERALS, NICKEL COMPOUNDS, ORES, OXIDE MINERALS, OXIDES, OXYGEN COMPOUNDS, POWER REACTORS, REACTOR COMPONENTS, REACTORS, SPECTROSCOPY, SURFACE COATING, THERMAL REACTORS, TRANSITION ELEMENT COMPOUNDS, TRANSITION ELEMENTS, WATER COOLED REACTORS, WATER MODERATED REACTORS, ZIRCONIUM COMPOUNDS
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