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Gorshunov, N.M.; Zotin, G.E.; Karchevskij, A.I.; Peshkov, A.T.
4. All-Russian (international) scientific conference. Physicochemical processes during selection of atoms and molecules. Collection of reports1999
4. All-Russian (international) scientific conference. Physicochemical processes during selection of atoms and molecules. Collection of reports1999
AbstractAbstract
[en] The analysis of the experimental and calculated data on isotopic enrichment of the nonequilibrium chemical reaction products with the participation of vibration excited molecules N2, CO, CO2 was conducted. The basic physical effects that operating in every case were revealed. It is shown that the quasi-equilibrium effect is responsible for the enrichment of intermediate products of the nonequilibrium chemical reactions with the participation of of the vibration excited molecules CO and N2. Five-fold enrichment of the C atoms by the 13C isotope and more than tenfold - for the N atoms by the 15N isotope is seen
[ru]
Проведен анализ экспериментальных и расчетных данных о изотопном обогащении продуктов неравновесных химических реакций с участием колебательно возбужденных молекул N2, CO, CO2. Выявлены основные физические эффекты, действующие в каждом случае. Показано, что квазиравновесный эффект приводит к обогащению промежуточных продуктов неравновесных химических реакций с участием колебательно возбужденных молекул CO и N2. Наблюдалось пятикратное обогащение атомов С изотопом 13C и более чем десятикратное для атомов N по изотопу 15NOriginal Title
Izotopicheskie ehffekty pri khimicheskikh reaktsiyakh kolebatel'no vozbuzhdennykh molekul N2, CO, CO2
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Source
Baranov, V.Yu.; Kolesnikov, Yu.A. (eds.); Rossijskij Nauchnyj Tsentr Kurchatovskij Inst., Moscow (Russian Federation); Gosudarstvennyj Nauchnyj Tsentr Rossijskoj Federatsii Troitskij Inst. Innovatsionnykh i Termoyadernykh Issledovanij, Troitsk (Russian Federation); 271 p; 1999; p. 232-236; 4. All-Russian (international) scientific conference. Physicochemical processes during selection of atoms and molecules; 4. Vserossijskaya (mezhdunarodnaya) nauchnaya konferentsiya. Fiziko-khimicheskie protsessy pri selektsii atomov i molekul; Zvenigorod (Russian Federation); 4-8 Oct 1999; 9 refs.; 5 figs.
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