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Karbowiak, M.; Sobczyk, M.; Drozdzynski, J., E-mail: jd@wchuwr.chem.uni.wroc.pl2003
AbstractAbstract
[en] Temperature-dependent line width and line shift measurements between 7 and 280 K have been performed for a number of absorption transitions in the 4000-21,000 cm-1 energy range of the U3+:LaCl3, Nd3+:LaCl3 and U3+:LaBr3 single crystal spectra. The values of the electron-phonon coupling parameter α-bar were determined for U3+:LaCl3 and Nd3+:LaCl3 by a fit of experimentally observed line widths to an equation containing the temperature dependent broadening due to the Raman two-phonon process. For both ions diluted in LaCl3 the values of the α-bar parameters are considerably lower than in K2LaCl5, and the value of α-bar for U3+ in the LaCl3 host is markedly larger as compared with that of Nd3+. Factors influencing these differences are discussed. With a temperature increase a blue shift of the absorption lines of the U3+ ions in LaCl3 and LaBr3 is observed. A comparison has been performed among the electron-phonon coupling parameters obtained from an analysis of the line widths of the U3+:LaCl3 single crystal and those determined from temperature induced line shifts as well as between the magnitudes of the absolute increase in line width and line shifts in the 7-290 K temperature range for U3+ doped LaCl3 and LaBr3 crystals. The electron-phonon coupling is stronger for U3+ in the tribromide as compared with the trichloride host which is mainly due to a larger covalency of the first one
Source
S0022459603000896; Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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ABSORPTION SPECTRA, COVALENCE, DOPED MATERIALS, ELECTRON-PHONON COUPLING, LANTHANUM BORIDES, LANTHANUM CHLORIDES, LINE BROADENING, LINE WIDTHS, MONOCRYSTALS, NEODYMIUM IONS, RAMAN SPECTRA, SPECTRAL SHIFT, TEMPERATURE DEPENDENCE, TEMPERATURE RANGE 0013-0065 K, TEMPERATURE RANGE 0065-0273 K, URANIUM IONS
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