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AbstractAbstract
[en] The A1-symmetry Raman spectra of berlinite in a broad temperature range, encompassing the α-β phase transition, are reported. The temperature dependence of the lattice mode parameters is presented, particularly concerning the 'soft' mode at ∼220 cm-1, which exhibits a complex behaviour in the α phase. This is accounted for by coupling with another A1 mode and two-phonon background in the α phase. It is shown that the soft-mode parameters do not show appreciable discontinuities at the transition. The fact that four Raman active A1 modes instead of three are observed in the hexagonal β phase can be understood by assuming a dynamical disorder of Al and P atoms over trigonal α-phase sites
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S0953-8984(03)61727-3; Available online at http://stacks.iop.org/0953-8984/15/4487/c32516.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/; Country of input: International Atomic Energy Agency (IAEA)
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