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AbstractAbstract
[en] The microstructural evolution of a single crystal of yttria-stabilized zirconia (YSZ) implanted with Ti has been studied by cross-sectional transmission electron microscopy (TEM). The implantation of 180 keV Ti ions to a dose of 1x1017 ions/cm2 was completed at room temperature. After annealing at 1100 deg. C in an Ar atmosphere for 2 h, a phase transition from the fluorite structure of ZrO2 to an isometric pyrochlore structure-type, A2B2O7, occurred due to cation ordering. High-resolution TEM revealed nanodomains of pyrochlore, Y2(TixZr1-x)2O7, with a congruent with 10.24±0.05 Aa. The nanodomains of the pyrochlore phase, embedded within the YSZ fluorite substrate, occurred in a depth range from 45 to 105 nm below the surface, which corresponds to Ti concentrations from ∼10 to ∼15 at. %. The nanoscale pyrochlore precipitates and the YSZ matrix have a completely coherent orientation
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(c) 2002 American Institute of Physics.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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