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Svetlik, I.; Tomaskova, L.; Sus, F.
Workshop on radioanalytical methods 'IAA 03'. Summaries of lectures2003
Workshop on radioanalytical methods 'IAA 03'. Summaries of lectures2003
AbstractAbstract
[en] The method allows the isotope activities to be measured rapidly without the need to measure the transmutation curve from 90Y. Chemical treatment of samples includes selective separation of Sr with Sr Resin. The yield is determined by gamma spectrometry by measuring the activity of 85Sr added. The method was tested for Guardian and TriCarb instruments. The position of the measuring windows, basically determined by the maximum beta energies, depends on the quenching parameter of sample. The contributions from the blank, from the 85Sr added, fine corrections of the detection efficiency and transformation factors of residual activities were also calculated in dependence on the quenching parameter. The measuring windows at higher energies are more robust with respect to other interfering radionuclides. Residual activities in the various measuring windows are compared statistically and the presence of interfering radionuclides can be indicated. Windows W1 through W4 were defined. The maximum beta energies for 90Sr, 89Sr, 210Bi, and 90Sr are 2283, 1491, 1161, and 546 keV, respectively. The W1 window corresponds to the window for 90Y (from E(max) of 90Y to E(max) of 89Sr). The lower limit of W2 is determined by the maximum energy of 210Bi. So the interval between E(max) of 89Sr and 90Sr is divided into 2 parts, the higher-lying part being more robust with respect to the presence of the probable interfering radionuclides. W3 is an auxiliary window, usable for the indication of interfering effects. W4 can be used for the indication and/or direct measurement of activities of freshly isolated 90Sr, with a minor correction for increasing 90Y activity. The lower limit of W4 is fixed and defines a window with relatively lower corrections for 85Sr. Sample treatment consists of mineralization in a microwave oven, coprecipitation with hydrated Fe(OH)3 and MnO2, group isolation of Sr on a strongly basic annex in HCl, and isolation of Sr on a column packed with Sr Resin. The recovery of Sr lay within the range of 50%-90%. Typical detection limits for the TriCarb 3170 instrument were 10-40 mBq for 90Y and 50-200 mBq for 89Sr in sample (provided that 90Y is absent). (P.A.)
Original Title
Mereni 90Sr spolu s 89Sr kapalinovou scintilacni spektrometrii s moznosti indikace pritomnosti rusivych radionuklidu
Primary Subject
Source
Ioannes Marcus Marci Spectroscopic Society, Prague (Czech Republic); Czech Chemical Society, Prague (Czech Republic); 35 p; Nov 2003; p. 23-26; Workshop on radioanalytical methods 'IAA 03'; Seminar Radioanalyticke metody IAA 03; Prague (Czech Republic); 25 Jun 2003; 2 tabs., 2 figs., 13 refs.
Record Type
Miscellaneous
Literature Type
Conference
Report Number
Country of publication
ALKALINE EARTH ISOTOPES, ALPHA DECAY RADIOISOTOPES, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, BISMUTH ISOTOPES, CHEMICAL ANALYSIS, COUNTING TECHNIQUES, DAYS LIVING RADIOISOTOPES, EVEN-EVEN NUCLEI, EVEN-ODD NUCLEI, HEAVY NUCLEI, HOURS LIVING RADIOISOTOPES, INTERMEDIATE MASS NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MATERIALS, NUCLEI, ODD-ODD NUCLEI, PHOSPHORS, RADIOACTIVE MATERIALS, RADIOISOTOPES, STRONTIUM ISOTOPES, WASTES, YEARS LIVING RADIOISOTOPES, YTTRIUM ISOTOPES
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