Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.022 seconds
AbstractAbstract
[en] Magnetic structure determination of a few ferri- and antiferromagnets normal spinels has led us to study what are, besides nearest neighbour magnetic interactions, the magnetic terms which have to be considered in the establishment of such or such magnetic structure. Tetragonal distortion which is frequently observed in such compounds is of the order of magnetic exchange striction (10-3). Such a distortion leads to two effects. First it decreases the total energy of the system. Secondly it introduces term of axial magnetic anisotropy. Besides this term of axial anisotropy, the possibility of basal anisotropy in the case of coplanar magnetic structure has to be considered. This last term explained why the magnetic structures of such antiferromagnetic spinels frequently have one or more cell parameters which are twice that of the chemical cell. Finally the comparison between various magnetic structures of antiferromagnetic spinels in which the leading term is the magnetic energy between first nearest neighbours, shows that the part played by magnetic interactions between non nearest neighbours is not negligible. Such indirect superexchange interactions through two anions or two anions and a cation on tetrahedral site, although of the order of a few percent of the preceding one, join a given ion to its twelve second nearest neighbours, six third nearest neighbours and twelve fourth nearest neighbours. (author)
[fr]
La determination des structures magnetiques de quelques spinelles ferri- et antiferromagnetiques normaux nous a conduit a preciser quels sont, en dehors du terme dominant d'interaction magnetique entre ions premiers voiins, les termes d'energie magnetique a considerer dans l'apparition de telle ou telle structure magnetique. La distorsion quadratique que l'on observe frequemment dans ces composes est de l'ordre de grandeur de celle attribuable a la striction d'echange (10-3). L'effet d'une telle distorsion est double. Non seulement elle permet d'abaisser l'energie totale de ces composes mais elle introduit egalement un terme d'energie d'anisotropie axiale. A cote de cette energie d'anisotropie axiale, il faut egalement, dans le cas de structures coplanaires retenir la possibilite de l'existence d'une energie d'anisotropie basale dans le plan perpendiculaire a l'axe quadratique. Ce dernier terme d'energie d'anisotropie permet d'expliquer pourquoi les structures magnetiques antiferromagnetiques de tels spinelles normaux ont frequemment un ou plusieurs parametres doubles de celui de la maille chimique. Enfin la comparaison des structures magnetiques des spinelles antiferromagnetiques dans lesquels le terme d'energie magnetique dominant est le terme d'interaction magnetique entre ions premiers voisins met en evidence l'existence d'interactions magnetiques entre ions plus eloignes. De telles interactions de superechange indirect s'exercent soit par l'intermediaire de deux anions, soit par l'intermediaire de deux anions et d'un cation tetraedrique. Bien que de l'ordre de grandeur de quelques pour cent seulement des precedentes, l'importance de ces interactions n'est pas negligeable puisque de telles interactions relient un ion donne a ses douze seconds voisins, six troisiemes voisins et douze quatriemes voisins. (auteur)Original Title
Contribution a l'etude des interactions magnetiques dans quelques spinelles ferri-et antiferromagnetiques normaux etudies par diffraction des neutrons
Primary Subject
Source
1969; Dec 1968; [140 p.]; 78 refs.; These ES-sciences
Record Type
Report
Literature Type
Thesis/Dissertation
Report Number
Country of publication
ANISOTROPY, ANTIFERROMAGNETIC MATERIALS, BLOCH WALL, CHROMITES, COBALT COMPOUNDS, FERRIMAGNETIC MATERIALS, MAGNESIUM OXIDES, MAGNETIC MOMENTS, MAGNETIC SUSCEPTIBILITY, MANGANESE OXIDES, NEUTRON DIFFRACTION, ORTHORHOMBIC LATTICES, SELENIUM COMPOUNDS, SPIN, SPINELS, TETRAGONAL LATTICES, VANADIUM OXIDES
ALKALINE EARTH METAL COMPOUNDS, ANGULAR MOMENTUM, CHALCOGENIDES, CHROMIUM COMPOUNDS, COHERENT SCATTERING, CRYSTAL LATTICES, CRYSTAL STRUCTURE, DIFFRACTION, DOMAIN STRUCTURE, MAGNESIUM COMPOUNDS, MAGNETIC MATERIALS, MAGNETIC PROPERTIES, MANGANESE COMPOUNDS, MATERIALS, MINERALS, OXIDE MINERALS, OXIDES, OXYGEN COMPOUNDS, PARTICLE PROPERTIES, PHYSICAL PROPERTIES, SCATTERING, TRANSITION ELEMENT COMPOUNDS, VANADIUM COMPOUNDS
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue